Neptune is the eighth and farthest planet from the Sun in the Solar System. It is the fourth-largest planet by diameter and the third-largest by mass. Among the gaseous planets in the Solar System, Neptune is the most dense. Neptune is 17 times the mass of Earth and is slightly more massive than its near-twin Uranus, which is 15 times the mass of Earth, and not as dense as Neptune orbits the Sun at an average distance of 30.1 astronomical units. Named after the Roman god of the sea, its astronomical symbol is ♆, a stylised version of the god Neptune's trident.

Neptune was the first and only planet found by mathematical prediction rather than by empirical observation. Unexpected changes in the orbit of Uranus led Alexis Bouvard to deduce that its orbit was subject to gravitationalperturbation by an unknown planet. Neptune was subsequently observed on 23 September 1846 by Johann Galle within a degree of the position predicted by Urbain Le Verrier, and its largest moon, Triton, was discovered shortly thereafter, though none of the planet's remaining 13 moons were located telescopically until the 20th century. Neptune was visited by Voyager 2, when it flew by the planet on 25 August 1989.

Neptune's internal structure resembles that of Uranus. Its atmosphere forms about 5% to 10% of its mass and extends perhaps 10% to 20% of the way towards the core, where it reaches pressures of about 10 GPa, or about 100,000 times that of Earth's atmosphere. Increasing concentrations of methane, ammonia and water are found in the lower regions of the atmosphere.

The mantle is equivalent to 10 to 15 Earth masses and is rich in water, ammonia and methane.As is customary in planetary science, this mixture is referred to as icy even though it is a hot, dense fluid. This fluid, which has a high electrical conductivity, is sometimes called a water–ammonia ocean. The mantle may consist of a layer of ionic water in which the water molecules break down into a soup of hydrogen and oxygen ions, and deeper down superionic water in which the oxygen crystallises but the hydrogen ions float around freely within the oxygen lattice. At a depth of 7000 km, the conditions may be such that methane decomposes into diamond crystals that rain downwards like hailstones. Very-high-pressure experiments at the Lawrence Livermore National Laboratory suggest that the base of the mantle may comprise an ocean of liquid diamond, with floating solid 'diamond-bergs'.

The core of Neptune is composed of iron, nickel and silicates, with an interior model giving a mass about 1.2 times that of Earth. The pressure at the centre is 7 Mbar (700 GPa), about twice as high as that at the centre of Earth, and the temperature may be 5,400 K

Atmosphere

At high altitudes, Neptune's atmosphere is 80% hydrogen and 19% helium A trace amount of methane is also present. Prominent absorption bands of methane occur at wavelengths above 600 nm, in the red and infrared portion of the spectrum. As with Uranus, this absorption of red light by the atmospheric methane is part of what gives Neptune its blue hue, although Neptune's vivid azure differs from Uranus's milder cyan. Because Neptune's atmospheric methane content is similar to that of Uranus, some unknown atmospheric constituent is thought to contribute to Neptune's colour.

Neptune's atmosphere is subdivided into two main regions: the lower troposphere, where temperature decreases with altitude, and the stratosphere, where temperature increases with altitude. The boundary between the two, the tropopause, occurs at a pressure of 0.1 bars (10 kPa). The stratosphere then gives way to the thermosphere at a pressure lower than 10⁻⁵ to 10⁻⁴ microbars (1 to 10 Pa).The thermosphere gradually transitions to the exosphere.

Models suggest that Neptune's troposphere is banded by clouds of varying compositions depending on altitude. The upper-level clouds occur at pressures below one bar, where the temperature is suitable for methane to condense. For pressures between one and five bars (100 and 500 kPa), clouds of ammonia and hydrogen sulfide are believed to form. Above a pressure of five bars, the clouds may consist of ammonia, ammonium sulfide, hydrogen sulfide and water. Deeper clouds of water ice should be found at pressures of about 50 bars (5.0 MPa), where the temperature reaches 273 K (0 °C). Underneath, clouds of ammonia and hydrogen sulfide may be found.

High-altitude clouds on Neptune have been observed casting shadows on the opaque cloud deck below. There are also high-altitude cloud bands that wrap around the planet at constant latitude. These circumferential bands have widths of 50–150 km and lie about 50–110 km above the cloud deck. These altitudes are in the layer where weather occurs, the troposphere. Weather does not occur in the higher stratosphere or thermosphere. Unlike Uranus, Neptune's composition has a higher volume of ocean, whereas Uranus has a smaller mantle.

Neptune's spectra suggest that its lower stratosphere is hazy due to condensation of products of ultraviolet photolysis of methane, such as ethane and acetylene.The stratosphere is also home to trace amounts of carbon monoxide and hydrogen cyanide.The stratosphere of Neptune is warmer than that of Uranus due to the elevated concentration of hydrocarbons.